BT1.SEP | This file was created on 23 Jun'03 0:42 by ChemSep v4.50( C:\CHEMSEP\BT1.SEP) |
Column C:\CHEMSEP\BT1.SEP Components: Benzene Toluene Operation: Simple Distillation Total (Liquid product) Condenser Partial (Liquid product) Reboiler 10 Stages Feeds to stages 5 |----| |------>-----| | | |1 | | |--|------| |--|-| | | |----<-------->- |--|---|--| |--|---|--| ----->----5-|--|---|--| |--|---|--| |--|---|--| | |---|-----<----| |------|--| |--|-| |--->---------->- 10|----| Properties: Raoult's law K model Antoine Vapour pressure None Enthalpy Enthalpy reference state Vapour Enthalpy reference temperature 25.00 ( C) Formation enthalpies Excluded Exergy surroundings temperature 25.00 ( C) Reactions: Specifications: Column pressure Condenser pressure 1.115 (bar) Top pressure 1.115 (bar) Default efficiency = 1.000 (-) Feed 1 Stage 5 Pressure (bar) 1.115 Enthalpy (kJ/kmol) Vapour fraction (-) 0.0000 Temperature ( C) Component flows (mol/s) Benzene 5.874 Toluene 5.874 Condenser Reflux ratio = 2.000 (-) Initialization guess: * Reboiler Bottom product flow rate = 5.874 (mol/s) Initialization guess: * Solve options: Automatic Initialization Newton's method Flow Step limit 0.5000 (-) Temperature Step limit 10.00 ( C) Composition Step limit 1.000 (-) Accuracy = 0.0001 Maximum iterations = 30 Feeds type = Stage below User program = CSW
ChemSep - Flash/Col2 v4.00s Copyright(c) H.Kooijman and R.Taylor, 1988-2000 Checking data file F:\CS\WWW\CURRENT\DOWNLO~1\BT1.SEP Reading configuration Reading component property libraries Reading thermodynamic property options Reading specifications Checking Component Data Benzene Toluene Determining feed conditions Generating initial flow profiles Generating initial composition profiles Starting Newtons method Ctrl-Break will terminate execution Iteration Error 0 7.1364E-04 1 2.1626E-03 2 3.4729E-06 Convergence obtained in 2 iterations Generating equilibrium data
Mass and Energy Balances Stream / Apparatus Mass (mol/s) Energy (MW) Exergy (MW) Feed 1 11.75 0.0000 -0.8236 Top -5.873 -0.0000 0.3601 Bottom -5.874 -0.0000 0.4581 Condenser Duty 0.0000 0.0000 Reboiler Duty 0.0000 0.0000 ----------- + ----------- + ----------- + Balance -3.958E-05 0.0000 -0.005415 Thermodynamic efficiency = -0.0000 Component discrepancies (mol/s) Benzene -1.722E-05 Toluene -1.929E-05 Stage Temperature Pressure Flow rates (mol/s) ( C) (bar) Liquid Vapour Feed Product 1 85.09 1.115 11.75 5.873 L 2 87.14 1.115 11.75 17.62 3 89.85 1.115 11.75 17.62 4 92.88 1.115 11.75 17.62 5 95.71 1.115 23.49 17.62 11.75 6 98.02 1.115 23.49 17.62 7 101.1 1.115 23.49 17.62 8 104.7 1.115 23.49 17.62 9 108.0 1.115 23.49 17.62 10 110.6 1.115 17.62 5.874 L Profile for Toluene Stage Liquid (-) Vapour (-) K (-) 1 0.07432 0.03065 0.4124 2 0.1683 0.07432 0.4415 3 0.2839 0.1370 0.4825 4 0.4023 0.2140 0.5320 5 0.5037 0.2930 0.5817 6 0.5807 0.3630 0.6251 7 0.6772 0.4658 0.6878 8 0.7771 0.5943 0.7648 9 0.8628 0.7276 0.8432 10 0.9256 0.8419 0.9096 Profile for Toluene Stage Liquid (-) Vapour (-) K (-) 1 0.07432 0.03065 0.4124 2 0.1683 0.07432 0.4415 3 0.2839 0.1370 0.4825 4 0.4023 0.2140 0.5320 5 0.5037 0.2930 0.5817 6 0.5807 0.3630 0.6251 7 0.6772 0.4658 0.6878 8 0.7771 0.5943 0.7648 9 0.8628 0.7276 0.8432 10 0.9256 0.8419 0.9096 Stream Feed 1 Top Bottom Stage 5 1 10 Pressure (bar) 1.115 1.115 1.115 Vapour fraction (-) 0.0000 0.0000 0.0000 Temperature ( C) 95.60 85.09 110.6 Enthalpy (kJ/kmol) 0.0000 0.0000 0.0000 Entropy (J/kmol/K) 2.352E+05 2.057E+05 2.616E+05 Mole flows (mol/s) Benzene 5.874 5.437 0.4369 Toluene 5.874 0.4365 5.437 Total molar flow 11.75 5.873 5.874 Mole fractions (-) Benzene 0.5000 0.9257 0.07438 Toluene 0.5000 0.07432 0.9256 Mass flows (kg/s) Benzene 0.4588 0.4247 0.03413 Toluene 0.5412 0.04022 0.5010 Total mass flow 1.0000 0.4649 0.5351 Mass fractions (-) Benzene 0.4588 0.9135 0.06378 Toluene 0.5412 0.08651 0.9362
Liquid compositions
Vapor compositions
K-values
Temperatures
Pressures
Flow profiles
Enthalpies
Stripping factors
Key-ratios
Relative volatilities
McCabe-Thiele